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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 42, 2012 - Issue 3
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Original Articles

Two Manganese(II) and Zinc(II) Coordination Polymers Constructed From Imidazole Dicarboxylates: Synthesis, Crystal Structures, and Thermal Properties

Xinjiang Cao Department of Chemistry, Zhengzhou University, Zhengzhou, Henan, P. R. China
,
Zeli Yang Department of Chemistry, Zhengzhou University, Zhengzhou, Henan, P. R. China
,
Mengwei Guo Department of Chemistry, Zhengzhou University, Zhengzhou, Henan, P. R. China
,
Chengjie Wang Department of Chemistry, Zhengzhou University, Zhengzhou, Henan, P. R. China
&
Gang Li Department of Chemistry, Zhengzhou University, Zhengzhou, Henan, P. R. China
Pages 402-407 | Received 17 Mar 2011, Accepted 04 Aug 2011, Published online: 24 Apr 2012
 
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Abstract

Two coordination polymers, [Mn(Hmidc)(H2O)2]n (H3midc = 2-methyl-1H-imidazole-4,5-dicarboxylic acid) (1) and [Zn (Hpidc)(H2O)]n (H3pidc = 2-propyl-1H-imidazole-4,5-dicarboxy lic acid) (2), have been hydrothermally synthesized and characterized by means of elemental analysis, IR, and single-crystal X-ray diffraction. Both compounds 1 and 2 are one-dimensional chain structures in which imidazole carboxylate ligands bridge metal ions by μ 2-mode. Furthermore these chains join each other forming three-dimensional supramolecular networks through hydrogen bonds. The thermal stabilities of the two compounds have been also investigated.

Acknowledgments

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (21071127, and 20501017) and the Natural Science Foundation of Henan Educational Committee (2009A150028, 2011A150029).

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