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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 42, 2012 - Issue 4
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Original Articles

Hydrothermal Synthesis, Crystal Structure, and Luminescence Property of a New 4d-4f Complex Based on 5-(isonicotinamido)-isophthalate

Man-Sheng Chen Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, P. R. China
,
Yi-Fang Deng Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, P. R. China
,
Xue Nie Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, P. R. China
&
Chun-Hua Zhang Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, P. R. China
Pages 513-517 | Received 10 Jan 2011, Accepted 08 Aug 2011, Published online: 01 May 2012
 
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Abstract

Hydrothermal reactions of Ag2O, 5-(isonicotinamido) isophthalic acid as well as Eu2O3 with a drop of CH3COOH results in formation of a new 4d-4f heterometallic coordination polymer [AgEu(INAIP)2(H2O)]·(H2O) (1) (INAIP = 5-(isonicotinamido)isophthalate). X-ray single-crystal structural analysis reveals that 1 is a three-dimensional framework. Furthermore, 1 also displayed photoluminescent properties in the red range at room temperature.

Acknowledgments

This work was financially supported by the Distinguished Young Cadreman of Hunan Province (2008), Science Foundation of Hengyang Normal University of China (10B67) and the Scientific Research Fund of Hunan Provincial Education Department (No. 11K009).

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