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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 42, 2012 - Issue 8
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Original Articles

Assembly of a New Three-Dimensional Metal-Organic Framework With V-Shaped Carboxylate Ligand and Rigid N-Donor Ligand

Jian-Qiang Liu Guangdong Medical College, School of Pharmacy, Dongguan, P. R. China
,
Yun-Sheng Huang Guangdong Medical College, School of Pharmacy, Dongguan, P. R. China
&
Dao-Hua Xu Guangdong Medical College, School of Pharmacy, Department of Pharmacology, Dongguan, P. R. China
Pages 1115-1119 | Received 27 Sep 2011, Accepted 03 Jan 2012, Published online: 28 Aug 2012
 
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Abstract

A new inorganic-organic coordination polymer based on a “V” shape linking unit 3,3′,4,4′-oxydiphthalic acid (H4ODPA),1,2–bis (4-pyridyl)ethene(bpe) and Co(II) ions, [Co2(ODPA)(bpe)(μ2-H2O)]n (1), has been prepared and structurally characterized by single-crystal X-ray diffraction analysis. Compound 1 adopts a novel 3D CdSO4-type topological framework containing nanotube channels. Moreover, the coordination chemistry of ODPA ligand is also discussed.

Acknowledgments

This work was partially supported by the grants from Guangdong Medical College (B2010009), Foundation for Distinguished Young Talents in Higher Education of Guangdong, China (LYM11069), Technologies R & D program of Zhanjiang (2011C3108013), Science & Technology Innovation Fund of Guangdong Medical College (STIF201112).

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