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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 3
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Original Articles

A Three-Dimensional Heterometallic CuII–GdIII Coordination Polymer: Hydrothermal Synthesis, Crystal Structure, Thermal and Magnetic Properties

Zhao-Hao Li College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
,
Li-Ping Xue College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
,
Jia-Jia Li Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
,
Jian-Ge Wang College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
&
Bang-Tun Zhao College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, P. R. China
Pages 254-258 | Received 05 Nov 2011, Accepted 13 Oct 2012, Published online: 25 Jan 2013
 
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Abstract

A new 3d-4f coordination polymer, {[Gd2Cu(PDC)2(SO4)2 (H2O)6]·2H2O}n (I), has been synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that I crystallizes in triclinic system, space group P – 1. Unit cell parameters for I are a = 6.354(2), b = 10.027(2), c = 10.244(3) Å, α = 95.054(2)°, β = 95.098(1)°, γ = 99.818(1)°, V = 637.0(4) Å3, Z = 1. The compound is a three-dimensional network structure in which infinite lanthanide-carboxylate chains are linked by [Cu(SO4)2]2− metalloligands to form a mixed-metal coordination network. The magnetic measurements reveal antiferromagnetic behaviors of the compound.

Acknowledgments

The authors acknowledge the Natural Science Foundation of China (No. 21172105) and the Foundation of the Education Department of Henan Province (No. 2011A150021) for the financial support.

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