Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 3
Submit an article Journal homepage
161
Views
3
CrossRef citations to date
0
Altmetric
Original Articles

[Co(salen)(CN)2]− as Building Block for the Design of Heterobimetallic Systems: Synthesis, Characterization, and Crystal Structures of Cyano-Bridged CoIII-MnII Complexes

Daopeng Zhang College of Chemical Engineering, Shandong University of Technology, Zibo, P. R. China
,
Zengdian Zhao College of Chemical Engineering, Shandong University of Technology, Zibo, P. R. China
,
Kexun Chen College of Chemical Engineering, Shandong University of Technology, Zibo, P. R. China
&
Xia Chen College of Chemical Engineering, Shandong University of Technology, Zibo, P. R. China
Pages 273-278 | Received 08 Nov 2011, Accepted 13 Oct 2012, Published online: 25 Jan 2013
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

With trans-dicyanidecobalt(III) precursor K[Co(salen)(CN)2]· CH3OH (1) (H2salen = N,N′-bis(salicyl)ethylenediamine) as build- ing block and two Mn(II) compounds containing bulky anci- llary organic ligands as assembling segments, two new cyanide- bridged heterometallic CoIII-MnII complexes {[Co(salen)(CN)2]2 [Mn(bipy)2]}·2CH3OH (2) and }[Co(salen)(CN)2]2[Mn(phen)2]}· 0.5CH3CN·0.5H2O(3) have been successfully synthesized and characterized by elemental analysis, IR spectroscopy, and X-ray structure determination. Single X-ray diffraction analysis reveals the trinuclear V-shaped CoIII 2MnII nature of complexes 2 and 3 comprise one [Mn(bipy)2]2+/[Mn(phen)2]2+ and two [Co(salen)(CN)2]− units. Interestingly, under the help of intermolecular C-H…π interactions, both of these two complexes display two dimensional supermolecular structures.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (21171107), the Natural Science Foundation of Shandong Province (ZR2011BM008), and the Science and Technology Project of High Education, Shandong Province (No. J11LB09).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

[Fe(bpb)(CN)2]- as a Versatile Building Block for the Design of Novel Low-Dimensional Heterobimetallic Systems: Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged FeIII−NiII Complexes [(bpb)2- = 1,2-Bis(pyridine-2-carboxamido)benzenate]
Source: (:unav)
Photomagnetism in clusters and extended molecule-based magnets.
Source: HAL CCSD
Crystalline-state reaction with allosteric effect in spin-crossover, interpenetrated networks with magnetic and optical bistability.
Source: Wiley
Slow dynamics of the magnetization in one-dimensional coordination polymers: single-chain magnets.
Source: HAL CCSD
CCDC 874225: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Rational Design and Assembly of a New Series of Cyanide-Bridged Fe −Mn One-Dimensional Single Chain Complexes: Synthesis, Crystal Structures, and Magnetic Properties
Source: (:unav)
A series of trinuclear sandwich-like cyanide-bridged iron(III)-manganese(II) complexes: synthesis, crystal structures, and magnetic properties
Source: Springer Science and Business Media LLC
Syntheses and X-ray crystal structures of cis-[Mn(bipy)2Cl2] · 2H2O · EtOH and cis-[Mn(phen)2Cl2] (bipy = 2,2′-bipyridine; phen = 1,10-phenanthroline); catalysts for the disproportionation of hydrogen peroxide
Source: Elsevier BV
{Co Mn } corrugated chains based on heteroleptic cyanido metalloligands
Source: (:unav)
Recent Advances in Applications of Room-Temperature Ionic Liquid/Supercritical CO2 Systems
Source: Wiley
Crystalline-state reaction with allosteric effect in spin-crossover, interpenetrated networks with magnetic and optical bistability.
Source: Wiley
[MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide‐Bridged Nanosized Molecular Wheel
Source: Wiley
Raising the Spin-Reversal Barrier in Cyano-Bridged Single-Molecule Magnets: Linear MnIII2MIII(CN)6 (M = Cr, Fe) Species Incorporating [(5-Brsalen)Mn]+ Units
Source: (:unav)
Optically Switchable Molecular Solids: Photoinduced Spin-Crossover, Photochromism, and Photoinduced Magnetization
Source: American Chemical Society (ACS)
Substituent Effect on Formation of Heterometallic Molecular Wheels:  Synthesis, Crystal Structure, and Magnetic Properties
Source: American Chemical Society (ACS)
Molecular cube of Re(II) and Mn(II) that exhibits single-molecule magnetism.
Source: (:unav)
Three K[M(salen)(CN)2]-based trinuclear sandwich-like heterobimetallic M(III)–Cu(II) (M = Fe, Cr, Co) complexes: synthesis, crystal structures, and magnetic properties
Source: Springer Nature
Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Copper(I) Bimetallic 1−3D Metal−Organic Frameworks
Source: American Chemical Society (ACS)
mer-[Fe(pcq)(CN)3]-: a novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion].
Source: (:unav)
[MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide‐Bridged Nanosized Molecular Wheel
Source: Wiley
A Trigonal-Bipyramidal Cyanide Cluster with Single-Molecule-Magnet Behavior: Synthesis, Structure, and Magnetic Properties of {[MnII(tmphen)2]3[MnIII(CN)6]2}
Source: Wiley
Assembly of azido- or cyano-bridged binuclear complexes containing the bulky [Mn(phen)2]2+ building block: syntheses, crystal structures, and magnetic properties.
Source: (:unav)
Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(iii)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(iii) containing co-crystallized bulk anions and cations
Source: Royal Society of Chemistry (RSC)
CCDC 874227: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 6H2O Prussian Blue Analog
Source: American Chemical Society (ACS)
A room-temperature organometallic magnet based on Prussian blue
Source: HAL CCSD
CCDC 874226: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Photoswitchable Heterotrimetallic Chain Based on Octacyanomolybdate, Copper, and Nickel: Synthesis, Characterization, and Photomagnetic Properties
Source: American Chemical Society (ACS)
Spin-Crossover Behavior in Cyanide-bridged Iron(II)−Gold(I) Bimetallic 2D Hofmann-like Metal−Organic Frameworks§
Source: American Chemical Society (ACS)
[Fe(bpym)(CN)4]-: a new building block for designing single-chain magnets.
Source: (:unav)
Electrochemically Tunable Magnetic Phase Transition in a High-Tc Chromium Cyanide Thin Film
Source: American Association for the Advancement of Science (AAAS)
Tuning the Magnetic Behavior via Dehydration/Hydration Treatment of a New Ferrimagnet with the Composition of K0.2Mn1.4Cr(CN)6·6H2O
Source: (:unav)
Trinuclear {M1}CN{M2}2 complexes (M1= CrIII, FeIII, CoIII; M2= CuII, NiII, MnII). Are single molecule magnets predictable?
Source: (:unav)
New cyanide-bridged MnIII–MIII heterometallic dinuclear complexes constructed from [MIII(AA)(CN)4]− building blocks (M = Cr and Fe): synthesis, crystal structures and magnetic properties
Source: Royal Society of Chemistry (RSC)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.