Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 3
Submit an article Journal homepage
149
Views
2
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis and Characterization of Zinc(II) and Cadmium(II) Mixed Ligand Trichloroacetate Complexes

Sukhjinder Singh Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh, India
,
Deepika Saini Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh, India
,
S. K. Mehta Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh, India
&
Duane Choquesillo-Lazarte Laboratorio de Estudios Cristalográficos, IACT-CSIC, Armilla, Spain
Pages 283-288 | Received 12 Nov 2011, Accepted 13 Oct 2012, Published online: 25 Jan 2013
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

Mixed ligand, iso-structural zinc(II), [Zn(L1)2(L2)2] 1 and cadmium(II), [Cd(L1)2(L2)2] 2, (L1 = CCl3COO−, L2 = N,N,N′,N′-tetramethylethylenediamine (tmen)), trichloroacetate complexes have been prepared and characterized by elemental, spectroscopic (ir, nmr), thermogravimetry, molar conductivity, and X-ray studies in 2. The trichloroacetate acts as a monodentate and tmen ligand L2 functions as a bidentate ligand in both the complexes. The crystal structure of 2 is of monoclinic system, space group P21/n with a = 8.3302(19) Ǻ, b = 17.756(4) Ǻ, c = 18.619(4) Ǻ, β = 100.393(3)°, and V = 2708.8(10) Ǻ3, Z = 4. The geometry around the metal is distorted octahedral.

Acknowledgments

Ms. Deepika Saini gratefully acknowledges the meritorious fellowship as a financial assistance from U. G. C., New Delhi, India. The project “Factoría de Cristalización, CONSOLIDER INGENIO-2010” provided X-ray structural facilities for this work.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination
Source: Elsevier BV
Syntheses and characterization of two monomeric zinc complexes containing aqua ligands
Source: Elsevier BV
Anhydrous metal trifluoroacetates
Source: Royal Society of Chemistry (RSC)
A short history of SHELX
Source: International Union of Crystallography (IUCr)
The dinuclear unit μ-aqua-bis(μ-carboxylato)dimetal. X-ray structure and magnetism of cobalt and nickel(II) compounds containing bridging carboxylato groups and a bridging water molecule
Source: Elsevier BV
Synthesis, characterization and structural studies of mono- and polynuclear complexes of zinc(II) with 1,10-phenanthroline, 2,2′-bipyridine and 4,4′-bipyridine
Source: Elsevier BV
General definition of ring puckering coordinates
Source: American Chemical Society (ACS)
Aerosol-assisted chemical vapour deposition (AACVD) of silver films from triorganophosphine adducts of silver carboxylates, including the structure of [Ag(O2CC3F7)(PPh3)2]
Source: Elsevier BV
The structure of μ-aqua-bis(μ-trifluoroacetato-O,O')-bis[(N,N,N',N'-tetramethylethylenediamine)(trifluoroacetato)nickel(II)]
Source: International Union of Crystallography (IUCr)
[Zn(phen)2(CX3COO)]+, X = H orCl; Influence of X on the Coordination Mode of the Carboxylate Group (phen = 1,10-Phenanthroline)
Source: Walter de Gruyter GmbH
Reactions of sterically hindered organozinc and organocadmium compounds containing functional silicon centres. Crystal structures of Zn[C(SiMe3)2(SiMe2OCOCF3)]2 and Cd[C(SiMe3)2(SiMe2OMe)]2
Source: Elsevier BV
CCDC 839095: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Thermal and Structural Studies of a 1D Zinc(II) Coordination Polymer – [Zn(μ‐4,4′‐bipy)(H2O)4]n(CCl3COO)2n·(4,4′‐bipy)2n (4,4′‐bipy = 4,4′‐bipyridine), with Shorted Cl···Cl Interactions
Source: Wiley
Notes for authors 2011
Source: International Union of Crystallography (IUCr)
Coordination modes of 3-hydroxypicolinic acid (OH-picH): Synthesis and characterization of cadmium(II) complexes
Source: Elsevier BV
Two novel Zn(II) helical chain polymers containing both bridging and terminal carboxylato groups
Source: Elsevier BV
Bis(thiourea-κS)bis(trichloroacetato-κO)zinc(II) monohydrate
Source: International Union of Crystallography (IUCr)
Molecular Recognition within a Rigid Host: Structural Changes Induced in ?-Carboxylato Dimetal(II) Complexes by Replacing Steric Repulsions with Hydrogen Bonds
Source: Wiley
Syntheses and Structures of Three Mononuclear Coordination Compounds Containing Six- and Seven-Coordinated Manganese(II) Ions
Source: Walter de Gruyter GmbH
Syntheses, structures, and fluxionality of blue luminescent zinc(II) complexes: Zn(2,2',2"-tpa)Cl2, Zn(2,2',2"-tpa)2(O2CCF3)2, and Zn(2,2',3"-tpa)4(O2CCF3)2 (tpa = tripyridylamine).
Source: American Chemical Society (ACS)
Synthesis, spectroscopic, and thermal analyses of binuclear mixed ligand Co(II) and Ni(II) complexes
Source: Informa UK Limited
Synthesis and Reactivity of Haloacetato Derivatives of Iron(II) Including the Crystal and the Molecular Structure of [Fe(CF3COOH)2(μ-CF3COO)2]n
Source: American Chemical Society (ACS)
Syntheses and crystal structures of bis(4-dimethylaminopyridine) group 12 trifluoroacetates — M(OCOCF3)2·2DMAP (M=Zn, Cd, Hg)
Source: Elsevier BV
Synthesis, and crystal and molecular structures of the triflato and trifluoroacetato complexes of zinc, Zn(O3SCF3)2(DME)2 and [Zn(O2CCF3)2(DME)]n
Source: Elsevier BV
Structure of bis(2-methyl-1,2-propanediamine-N,N')bis(trichloroacetato-O)nickel(II), [Ni(C2Cl3O2)2(C4H12N2)2]
Source: International Union of Crystallography (IUCr)
A novel variation on a classical dimeric structure type. Preparation and structure of the metal-nitroxyl complex [Cu(O2CCCl3)2(Tempo)]2
Source: American Chemical Society (ACS)
The use of conductivity measurements in organic solvents for the characterisation of coordination compounds
Source: Elsevier BV
Polyether Adducts of d-Block Metal Compounds as Starting Materials for New Cluster Compounds
Source: Wiley
Synthesis and structure of a heptacoordinated cadmium(II) complex
Source: Elsevier BV

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.