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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 9
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Original Articles

Oxidative Cyclization and Structure of A Cu(II) Complex Bearing Thiourea-Based Ligand

Xuesong Lin Department of Chemistry and Chemical Engineering, Chifeng University, Chifeng, Neimenggu, P. R. China
,
Xiaochun Li Department of Chemistry and Chemical Engineering, Chifeng University, Chifeng, Neimenggu, P. R. China
,
Wenmin Xiao Department of Chemistry and Chemical Engineering, Chifeng University, Chifeng, Neimenggu, P. R. China
&
Yali Sang Department of Chemistry and Chemical Engineering, Chifeng University, Chifeng, Neimenggu, P. R. China
Pages 1099-1102 | Received 09 May 2012, Accepted 03 Dec 2012, Published online: 14 May 2013
 
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Abstract

An unprecedented complex, namely, [Cu(L2)2] (HL2 from the designed ligand, N-(2-hydroxyethyl)-N’-benzoylthiourea (H3L1)) (1), has been obtained successfully from the reaction of Cu(NO3)2 . 3H2O and H3L1 in methanol-water solution. Its crystal structure, IR, and thermal properties are described. Also, the reaction mechanism has been proposed.

Acknowledgments

The authors gratefully acknowledge the financial support by the Research Program of Universities of Inner Mongolia Autonomous Region (NJ10245).

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Related Research Data

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