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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 9
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Original Articles

A New Cd(II) Coordination Polymer Constructed From Dicarboxylate and N-donor Ligand: Synthesis, Crystal Structure, and Luminescence Property

Aidong Wang Department of Chemistry, College of Huangshan, Huangshan, P. R. China; University of Science and Technology of China, Hefei, Anhui, P. R. China
,
Fengkai Hu Department of Chemistry, College of Huangshan, Huangshan, P. R. China
,
Zhongcheng Ke Department of Chemistry, College of Huangshan, Huangshan, P. R. China
,
Chen Fang Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, P. R. China
&
Wei Wei Department of Chemistry, College of Huangshan, Huangshan, P. R. China
Pages 1146-1149 | Received 21 Nov 2012, Accepted 03 Dec 2012, Published online: 14 May 2013
 
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Abstract

The 3D coordination polymer {[Cd(dpa)(bpe)]·2H2O}n (1)[H2dpa = 2,4′-biphenyl dicarboxylic acid and bpe = 1,2-bis(4-pyridyl)ethane] was prepared by hydrothermal synthesis and characterized by single X-ray diffraction, FTIR spectra and element analysis. The title complex 1 exhibits an unusual three-dimensional framework with (6,6)-connected (32.42.52.68.8) (34.44.54.63) topology. Furthermore, the solid-state photoluminescence property of 1 is investigated at room temperature.

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