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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 10
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Original Articles

Two New Ion-Pair Complexes Based on Bis(iso-maleonitriledithiolate)nickelate(II) Anion and Substituted Pyridinium/Quinolinium: Syntheses, Weak Interactions, and 3D Structures

Jin-Fang Liu Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Li-Bo Liang Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Shu-Lin Dai Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Rui-Kang Huang Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Qiu-Ying Guan Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Wei-Qiang Chen Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Le-Min Yang Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
,
Jia-Rong Zhou Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
&
Chun-Lin Ni Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China
 show all
Pages 1492-1500 | Received 26 Feb 2012, Accepted 25 Dec 2012, Published online: 25 Aug 2013
 
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Abstract

Two new ion-pair complexes, based on [Ni(i-mnt)2]2– (i-mnt = isomaleonitriledithiolate) anion, [Bz-4-MePy]2[Ni(i-mnt)2]([Bz-4- MePy]+ = 1-benzyl-4′-methylpyridinium) (1) and [Bz-4-MeQl]2 [Ni(i-mnt)2]([Bz-4-MeQl]+ = 1-benzyl-4′-methylquinolinium) (2), were obtained and characterized. The most obvious structure feature of 1 and 2 is that the [Ni(i-mnt)2]2– anions form a 1D chain through C···N or C···C short interactions between the i-mnt ligands, and the [Bz-4-MeQl]+ cations of 2 form a 2D structure through the π···π stacking interactions between the aromatic rings. The C–H···N and C–H···Ni hydrogen bonds observed in the anions and cations consolidate the stacking of the molecules and give rise to a 3D network structure.

Acknowledgments

This work has been partially supported by the Science and Technology Project (No. 2012B010200041, No. 2011B080701026) from Guangdong Science and Technology Department, the key Academic Program of the 3rd phase “211 Project” of South China Agricultural University (No. 2009B010100001), and the university students’ innovative experimental project (No.1056411140) from Education Department of Guangdong Province.

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