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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 10
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Original Articles

Syntheses, Crystal Structures, and Photoluminescent Properties of Zn(II) and Ag(I) Coordination Polymers Based on 1H-1,2,4-triazole-1-methylene-1H-benzimidazole

Jing Cao Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, P. R. China
,
Wen-Ting Deng Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, P. R. China
,
Jun-Jun Yao Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, P. R. China
&
Jia-Cheng Liu Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, Key Laboratory of Bioelectrochemistry & Environmental Analysis of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, P. R. China
Pages 1525-1531 | Received 01 Jun 2012, Accepted 29 Dec 2012, Published online: 25 Aug 2013
 
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Abstract

The title ligand, 1H-1,2,4-triazole-1-methylene-1H-benzimida- zole (L), and its two new derivatives, [ZnL2Cl2]n (1) and [AgL(NO3)]n (2), were synthesized and characterized by X-ray single diffraction, IR and elemental analysis. Owing to the greater distribution of the electron density associated with the benzimidazoyl and triazoyl units of L, the supramolecular frameworks of L, 1, and 2 are dominated by hydrogen bonding or π…π interactions in the solid state. In additional, the photoluminescent properties of L, 1, and 2 were also described.

Acknowledgments

The authors are thankful for support of this study by the National Natural Science Foundation of China (No. 20871099) and Gansu provincial Natural Science Foundation of China (No. 0710RJZA113).

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