Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 43, 2013 - Issue 10
Submit an article Journal homepage
80
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Construction of Two Different Topological Frameworks of Mn(II) Coordination Polymers Based on the Dicarboxylate and Imidazole-Containing Ligands

Aidong Wang Department of Chemistry, College of Huangshan, Huangshan, P. R. China; Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong China
,
Fengkai Hu Department of Chemistry, College of Huangshan, Huangshan, P. R. China
,
Zhongcheng Ke Department of Chemistry, College of Huangshan, Huangshan, P. R. China
,
Chen Fang University of Science and Technology of China, Hefei, Anhui, P. R. China
&
Wei Wei Department of Chemistry, College of Huangshan, Huangshan, P. R. China
Pages 1571-1575 | Received 11 Dec 2012, Accepted 29 Dec 2012, Published online: 25 Aug 2013
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

Two new Mn(II) coordination polymers, {[Mn(5-CH3-ip)(bib)]·2H2O}n (1) and [Mn (5-CH3- ip)(bib)0.5]n (2) (5-CH3-ip = 5-Methyl-1,3-benzenedicarboxylic acid bib = 1,4-bis(imidazol-1-yl) benzene), have been synthesized and characterized by elemental analysis, IR, and X-ray diffraction. Complex 1 shows a 2D layer structure. Complex 2 is a 3D structure (3,7)-connected topology with a Schäfli symbol of (620.8).(63). The topology has been well controlled by pH value.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Three new pyridine-2,6-dicarboxylate copper(II) compounds with coordinated pyridine-based ligands: Synthesis, characterisation and crystal structures
Source: Elsevier BV
CCDC 915039: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Tuning Structural Topologies of Three Photoluminescent Metal–Organic Frameworks via Isomeric Biphenyldicarboxylates
Source: American Chemical Society (ACS)
A pillared-bilayer porous coordination polymer with a 1D channel and a 2D interlayer space, showing unique gas and vapor sorption
Source: Royal Society of Chemistry (RSC)
A lacuna in reticular chemistry: an unprecedented binodal (6,10)-connected network based on two distinct zinc clusters
Source: Royal Society of Chemistry (RSC)
CCDC 915040: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Metal-controlled structural diversity in Co(II) and Zn(II) complexes with mixed N- and O-donors: Synthesis, characterization and property
Source: Elsevier BV
Interpenetrated and polycatenated nets of Cd(II) coordination networks from mixed N,N′-dipyridyladipoamide and dicarboxylate ligands
Source: Royal Society of Chemistry (RSC)
Metal–organic frameworks constructed from flexible V-shaped ligands: adjustment of the topology, interpenetration and porosity via a solvent system
Source: Royal Society of Chemistry (RSC)
Interrupted Zeolite LTA and ATN-Type Boron Imidazolate Frameworks
Source: American Chemical Society (ACS)
pH-Dependent Assembly of 1D to 3D Octamolybdate Hybrid Materials Based on a New Flexible Bis-[(pyridyl)-benzimidazole] Ligand
Source: American Chemical Society (ACS)
Magnetic Nanosized {M }-Wheel-Based (M = Co, Ni) Coordination Polymers
Source: (:unav)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.