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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 2
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Original Articles

Preparation, X-Ray Structures, and Cytotoxic Property of Mononuclear Schiff Base Zinc Complexes [Zn(SalPr)2] and [ZnI2(SalPt)2]

Nong Wang School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, P. R. China; Engineering and Technology Center of Gansu Province for Botanical Pesticides, Lanzhou Jiaotong University, Lanzhou, P. R. China
,
Lixuan Chen School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, P. R. China
,
Lijuan Yang School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, P. R. China
&
Yumei Wan School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, P. R. China
Pages 315-319 | Received 17 Jan 2013, Accepted 24 Jan 2013, Published online: 21 Oct 2013
 
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Abstract

Schiff bases obtained from 5-chlorosalicylaldehyde with cyclopropylamine, and 4-methoxysalicylaldehyde with cyclopentylamine, were used as ligands for Zn(II) resulting in two mononuclear zinc complexes, [Zn(SalPr)2] and [ZnI2(SalPt)2], where SalPr is 4-chloro-2-(cyclopropyliminomethyl)phenolate and SalPt is 2-(cyclopentyliminiummethyl)-5-methoxyphenolate. The detailed structures of the complexes were determined by single crystal X-ray crystallography. Coordination sphere of Zn(II) atoms in both complexes are slightly distorted tetrahedron. The cytotoxic property of the complexes was evaluated.

Acknowledgments

This work was supported by the Science and Technology Support Projects of Gansu Province (Grant No. 1204NKCA107), the Engineering and Technology Center Projects of Gansu (Grant No. 1106NTGA013), and ‘Qing Lan’ Talent Engineering Funds of Lanzhou Jiaotong University.

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