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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 44, 2014 - Issue 4
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Original Articles

A Bismuth(III) Coordination Polymer With Pyridine-2,3-dicarboxylic Acid as Precursor for Preparation of Bi2O3 Nanoparticles via Thermal Decomposition

Masoumeh Tabatabaee Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
,
Saeed Amjad Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
,
Sommayeh Tabatabaei Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
&
Krešimir Molčanov Department of Physical Chemistry, Rudjer Bošković Institute, Zagreb, Croatia
Pages 507-513 | Received 28 Jan 2013, Accepted 10 Feb 2013, Published online: 21 Nov 2013
 
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Abstract

A novel 1D-Bismuth(III) coordination polymer, {(4-Hmapy)[(μ-2,3-pydc)(2,3-pydcH)Bi(NO3)].2H2O}n (1) (pydc H2 = pyridine-2,3-dicarboxylic acid, 4-mapy = 2-amino-4-methylpyridine) has been synthesized and characterized by elemental analysis and IR spectroscopy as well as by X-ray structure analysis. Thermal decomposition of 1 in the peresence of polyethylene glycol led to nanoparticles of Bi2O3. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to characterize the structure and morphology of synthesized powder. The powder XRD pattern established the formation of Bi2O3 with α polymorph structure.

Acknowledgments

This research was supported by the Islamic Azad University, Yazd Branch, Iran and Ministry of Science, Education and Sports, Republic of Croatia, grant no. 0098-1191344-2943.

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