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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 3
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Original Articles

A New Luminescent Zn(II) Coordination Polymer Based on Mixed Ligands of Pyrazine-2,3-Dicarboxylic Acid and 3-Amino-1,2,4-Triazole

Ya-Ru LiuSchool of Science, North University of China, Taiyuan, P. R. ChinaCorrespondence[email protected]
,
Guo-Rui LiangSchool of Science, North University of China, Taiyuan, P. R. China
&
Zhi-Xian WieSchool of Science, North University of China, Taiyuan, P. R. China
Pages 319-322 | Received 29 May 2013, Accepted 27 Jul 2013, Published online: 09 Sep 2014
 
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Abstract

A new luminescent coordination polymer, namely [Zn(pzdc)(AmTAZ)]n (1 H2pzdc = pyrazine-2,3-dicarboxylic acid, AmTAZ = 3-amino-1,2,4-triazole), has been successfully synthesized under hydrothermal conditions. Single-crystal X-ray analysis reveals that 1 is a two-dimensional (2D) layered structure with the terminal AmTAZ ligands dangling up and down the layer. Finally, these 2D layers are further extended into a three-dimensional (3D) supramolecular framework through intermolecular hydrogen bonds.

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