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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 3
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Original Articles

Employing Trinuclear [Zn3(COO)4] Cluster as Building Subunits to Construct a New Luminescent Coordination Polymer

Yan ChengDepartment of Pharmacy, Mudanjiang Medical University, Heilongjiang, P. R. China
&
Jing GaoDepartment of Pharmacy, Mudanjiang Medical University, Heilongjiang, P. R. ChinaCorrespondence[email protected]
Pages 333-336 | Received 24 Jun 2013, Accepted 27 Jul 2013, Published online: 09 Sep 2014
 
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Abstract

A new Zn(II) coordination polymer, namely [Zn3(L)2(MA)2(H2O)2]n (1 H3L = biphenyl-3, 4’, 5-tricarboxylic acid, MA = melamine), has been synthesized by the reactions of Zn(II) ions with H3L in N, N-dimethylacetamide (DMA) solution. Single-crystal X-ray analysis reveals that 1 features a two-dimensional layer framework based on trinuclear [Zn3(COO)4] clusters as building subunits. In addition, the luminescent property of 1 was also investigated in the solid state at room temperature.

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