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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 3
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Original Articles

Synthesis and Characterization of a Novel Cadmium-Biimidazole Compound With a 1-D Chain-Like Motif

Wen-Tong ChenInstitute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji’an, Jiangxi, P. R. China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. ChinaCorrespondence[email protected]
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Pages 315-318 | Received 08 Aug 2013, Accepted 29 Aug 2013, Published online: 09 Sep 2014
 
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Abstract

A new cadmium-biimidazole compound, [Cd(2,2′-biimidazole)2(ClO4)]nnOH·2nH2O (1), has been obtained via solvothermal reactions and structurally characterized by X-ray single-crystal diffraction. Compound 1 crystallizes in the space group P21/c of the monoclinic system with four formula units in a cell: a = 6.8785(11), b = 17.938(3), c = 14.985(2) Å, β = 91.589(2)°, V = 1848.3(5) Å3, C12H17CdClN8O7, Mr = 533.19, Dc = 1.916 g/cm3, S = 1.048, μ(MoKα) = 1.383 mm−1, F(000) = 1064, R = 0.0326, and wR = 0.0900. Compound 1 is characteristic of an infinite one-dimensional chain-like structure.

Supplementary Material

Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Centre, CCDC No. 954524. Copies of this information may be obtained free of charge from the Director, CCDC, 12 Union Road, Cambridge, CBZ 1EZ, UK (Fax: +44–1223-336033; email: [email protected] or www:http://www.ccdc.cam.ac.uk).

Additional information

Funding

This work was supported by the NSF of Jiangxi Province (20132BAB203010), the National Science and Technology Support Program of the Ministry of Science and Technology of PR China (No. 2012BAC11B01), and the open foundation (No. 20130014) of the State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences.

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