Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 45, 2015 - Issue 12
Submit an article Journal homepage
140
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis, Crystal Structures, and Properties of Three Complexes of 5-(pyridin-2-ylmethoxy) Isophthalic Acid

Hong HaiCollege of Chemical and Bioengineering, (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, P. R. China
,
Hui WangCollege of Chemical and Bioengineering, (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, P. R. China
,
Wen Ying JinCollege of Chemical and Bioengineering, (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, P. R. China
,
Xiao Dong AnCollege of Chemical and Bioengineering, (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, P. R. China
,
Wen Gang HuangCollege of Chemical and Bioengineering, (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, P. R. China
&
Shu Hua ZhangCollege of Chemical and Bioengineering, (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, P. R. ChinaCorrespondence[email protected]
Pages 1870-1874 | Received 01 Nov 2013, Accepted 10 Nov 2013, Published online: 29 Jul 2015
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Three new coordination compounds, namely, [(HL)2M(H2O)4] (M = Co, (1); M = Mn, (2); M = Ni, (3), H2L = 5-(pyridin-2-ylmethoxy) isophthalic acid), have been hydrothermally synthesized and characterized by elemental analysis, IR, and single-crystal X-ray diffraction. The structures of complexes 1–3 are strikingly similar and the three complexes are mononuclear compounds. In complexes 1–3, the H2L ligand is partially deprotonated. In addition, the photoluminescent behavior of 2 and the H2L ligand has been investigated in detail.

Funding

This work is financially supported by the National Nature Science Foundation of China (No. 21161006) and Program for Excellent Talents in Guangxi Higher Education Institutions(Gui Jiao Ren [2012]41).

Supplementary Material

Crystallographic data (excluding structure factors) for the structures in this article have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication CCDC 969397–969399. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: 44 1223 336033, e-mail: [email protected]). The table of hydrogen bond parameters of complexes 1–3.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Novel Supramolecular Frameworks Self-Assembled from One-Dimensional Polymeric Coordination Chains
Source: Wiley
A Series of Cu(II) Complexes Based on Different Bis(imidazole) Ligands and Organic Acids: Formation of Water Clusters and Fixation of Atmospheric Carbon Dioxide
Source: American Chemical Society (ACS)
CCDC 969399: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Self-Assembly of a Series of Cobalt(II) Coordination Polymers Constructed from H2tbip and Dipyridyl-Based Ligands
Source: (:unav)
A family of cubane cobalt and nickel clusters: Syntheses, structures and magnetic properties
Source: Elsevier BV
CCDC 969397: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Multifunctionality and crystal dynamics of a highly stable, porous metal-organic framework [Zn4O(NTB)2].
Source: (:unav)
CCDC 969398: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Chain, Pillar, Layer, and Different Pores: A N-[(3-Carboxyphenyl)-sulfonyl]glycine Ligand as a Versatile Building Block for the Construction of Coordination Polymers
Source: (:unav)
Preparation, Adsorption Properties, and Catalytic Activity of 3D Porous Metal–Organic Frameworks Composed of Cubic Building Blocks and Alkali‐Metal Ions
Source: Wiley
Design, synthesis and fluorescence of two-dimensional pillared layers by connecting infinite one-dimensional chains via 4,4′-bipyridine
Source: Elsevier BV
A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
Source: American Chemical Society (ACS)
Synthesis, spectroscopic characterization and antimicrobial activity of binuclear metal complexes of a new asymmetrical Schiff base ligand: DNA binding affinity of copper(II) complexes
Source: Elsevier BV
Cd(II) Coordination Architectures with Mixed Ligands of 3-(2-Pyridyl)pyrazole and Pendant Carboxylate Ligands Bearing Different Aromatic Skeletons: Syntheses, Crystal Structures, and Emission Properties
Source: American Chemical Society (ACS)
pH-dependent self-assembly of divalent metals with a new ligand containing polycarboxylate: syntheses, crystal structures, luminescent and magnetic properties
Source: Royal Society of Chemistry (RSC)
Silver(I)−Polynitrile Network Solids for Anion Exchange: Anion-Induced Transformation of Supramolecular Structure in the Crystalline State
Source: American Chemical Society (ACS)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.