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Inorganic and Nano-Metal Chemistry Volume 47, 2017 - Issue 1
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Hydrothermal synthesis, crystal structure, and properties of a novel tetranuclear calcium complex constructed with aromatic sulfonate-carboxylate ligand

Lei GuanSchool of Chemistry and Materials Science, Liaoning Shihua University, Fushun, P. R. ChinaCorrespondence[email protected]
&
Ying WangSchool of Chemistry and Materials Science, Liaoning Shihua University, Fushun, P. R. China
Pages 31-36 | Received 23 Aug 2015, Accepted 27 Dec 2015, Published online: 24 May 2016
 
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abstract

A novel calcium complex, [Ca4(SIP)3(phen)8(H2O)6]·(Hphen)·(phen)·27H2O (1) (NaH2SIP = 5-sulfoisophthalic monosodium salt, phen = 1,10-phenanthroline), has been synthesized by hydrothermal reaction at 160°C. It was characterized by X-ray single-crystal diffraction, infrared spectroscopy, and elemental and thermogravimetric analysis. Complex 1 features an approximate U-shaped structure, where the tetranuclear calcium ions are bridged by tridentate and tetradentate SIP3− ligands, together with free 1H-protonated 1,10-phenanthroline balancing the charge. Each calcium ion is eight-coordinated showing distorted bicapped trigonal prism geometry. The luminescence spectrum indicates an emission maximum at 463 nm. Complex 1 shows a second harmonic generation response that is three times that of KH2PO4.

Funding

The authors thank Liaoning Province Education Department (No. L2015299) for financial support.

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