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Inorganic and Nano-Metal Chemistry Volume 47, 2017 - Issue 8
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Original Articles

Two novel MOFs constructed by tuning the metal ions—(HDMA)2·Cd3(FDA)4·DMF and (HDMA)·(HTEA)·Mn3(FDA)4 (DMA = dimethylamine, TEA = triethylamine, FDA = furan-2,5-dicarboxyl acid, and DMF = N,N′-dimethylformamide)

Huimin LiSchool of Chemical Engineering, Changchun University of Technology, Changchun, China
,
Shasha LiSchool of Chemical Engineering, Changchun University of Technology, Changchun, China
,
Yuanrui WangSchool of Chemical Engineering, Changchun University of Technology, Changchun, China
,
Yafeng LiSchool of Chemical Engineering, Changchun University of Technology, Changchun, China
&
Qian QiaoSchool of Chemical Engineering, Changchun University of Technology, Changchun, ChinaCorrespondence[email protected]
Pages 1186-1189 | Received 20 Jul 2015, Accepted 01 May 2016, Published online: 23 Mar 2017
 
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ABSTRACT

In this article, two novel metal-organic frameworks (MOFs) have been constructed by tuning the metal ions using identical ligand—FDA. Although both of them contain linear trinuclear secondary building unit (SBU) and infinite chain along with SBU, the different metal ions as node can result in the different connection of FDA. As a result, compound I shows 4,4-networks, and compound II contains 3-ring and 4-ring.

Funding

This work was supported by the National Science Foundation of China (No. 21171026).

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Related Research Data

Two novel MOFs constructed by tuning the metal ions—(HDMA)2·Cd3(FDA)4·DMF and (HDMA)·(HTEA)·Mn3(FDA)4 (DMA = dimethylamine, TEA = triethylamine, FDA = furan-2,5-dicarboxyl acid, and DMF = N,N′-dimethylformamide)
Source: Figshare
Two novel MOFs constructed by tuning the metal ions—(HDMA)2·Cd3(FDA)4·DMF and (HDMA)·(HTEA)·Mn3(FDA)4 (DMA = dimethylamine, TEA = triethylamine, FDA = furan-2,5-dicarboxyl acid, and DMF = N,N′-dimethylformamide)
Source: Figshare
CCDC 1413197: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
CCDC 1413196: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre

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