Synthesis, structure, and property of a two-dimensional layer coordination polymer on Ag(I)

Hui-Jie LunHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China

Qi ChenHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China

Hai-Jiao LiHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China

Yan-Long BaiHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China

Sa-Sa CuiHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China

Hai-Yan LiHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China

Shou-Bin WangHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China

Ya-Min LiHenan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, ChinaCorrespondence[email protected]

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ABSTRACT

By hydrothermal method, a new coordination polymer [Ag₃(btc)(dmt)(H₂O)]_n (1) (H₃btc = 1,3,5-benzenetricarboxylic acid, dmt = 2,4-diamino-6-methyl-1,3,5-triazine), has been synthesized and structurally characterized by IR spectrum, X-ray single diffraction, and elemental analysis. Compound 1 exhibits a planar 2D layer with 2-nodal (3,4)-connected {4.6²}₄{6⁴.10²} topology and further extends to 3D framework through hydrogen bond and Ag…O weak interactions. Moreover, compound 1 displays luminescent property at solid state and holds good catalytic activity toward photocatalytic degradation of RhB.

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Funding

This research is financially supported by the National Science Foundation of China (21271025, U1504209), the State Key Laboratory of Structural Chemistry (20150006), and Henan University (0000A40478).

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Synthesis, structure, and property of a two-dimensional layer coordination polymer on Ag(I)

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Synthesis, structure, and property of a two-dimensional layer coordination polymer on Ag(I)

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