Advanced search
Publication Cover
Inorganic and Nano-Metal Chemistry Volume 47, 2017 - Issue 7
Submit an article Journal homepage
140
Views
1
CrossRef citations to date
0
Altmetric
Articles

Synthesis, structure, and photocatalytic activity of a novel Ni (II) coordination polymer based on p-aminohippuric acid

Ziao ZongKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, China
,
Xiangmin MengKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, China
,
Xin LiKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, China
,
Caifeng BiKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, China
&
Yuhua FanKey Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, ChinaCorrespondence[email protected]
Pages 989-993 | Received 22 Sep 2015, Accepted 09 Jul 2016, Published online: 06 Mar 2017
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

ABSTRACT

A novel Ni(II) coordination polymer, {[Ni(C9H9N2O3)2(H2O)2]·H2O}n(1)(C9H11N2O3, p-Aminohippuric acid, PAH), has been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectra, and thermal analysis. Single-crystal X-ray analysis reveals that each Ni(II) ion is six-coordinated by two coordinated water molecules, two carboxylate oxygen atoms, and two nitrogen atoms from PAH forming a octahedral geometry. The complex features a 2-nodal 2,4-connected network with unprecedented Schläfli symbol of (42)(4)2. In addition, the photocatalytic studies indicate that this complex is a good candidate for the photocatalytic degradation of rhodamine B.

Funding

This research was supported by the National Natural Science Foundation of China to C.F. Bi (No. 21371161 and No. 21071134).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

In situ 2,5-pyrazinedicarboxylate and oxalate ligands synthesis leading to a microporous europium–organic framework capable of selective sensing of small molecules
Source: Royal Society of Chemistry (RSC)
Metal–organic frameworks constructed from flexible V-shaped ligands: adjustment of the topology, interpenetration and porosity via a solvent system
Source: Royal Society of Chemistry (RSC)
Metal-controlled structural diversity in Co(II) and Zn(II) complexes with mixed N- and O-donors: Synthesis, characterization and property
Source: Elsevier BV
Removal of synthetic dyes from wastewaters: a review.
Source: Elsevier BV
One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications
Source: American Chemical Society (ACS)
CCDC 1032747: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Two low-dimensional Schiff base copper(I/II) complexes: synthesis, characterization and catalytic activity for degradation of organic dyes
Source: (:unav)
Synthesis, crystal structure, and photodegradation properties of a new multicore Zn(II) metal organic framework
Source: Informa UK Limited
Water-Insoluble Heterometal-Oxide-Based Photocatalysts Effective for the Photo-Decomposition of Methyl Orange
Source: American Chemical Society (ACS)
pH-Dependent Assembly of 1D to 3D Octamolybdate Hybrid Materials Based on a New Flexible Bis-[(pyridyl)-benzimidazole] Ligand
Source: American Chemical Society (ACS)
MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF
Source: Elsevier BV
Synthesis, Characterization, and Photoluminescent Property of a New Zn(II) Coordination Polymer With Two-Fold Interpenetrating pcu Topology
Source: Informa UK Limited

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.