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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 21, 1991 - Issue 3
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Original Articles

Conversion of Acetals and Ketals to Carbonyl Compounds Promoted by ZrCl4-NaBH4

Wu Shaozu Department of Chemistry, Lanzhou University, Lanzhou, 730000, P. R China
,
Wang Huidong Department of Chemistry, Lanzhou University, Lanzhou, 730000, P. R China
&
Cheng Ning Department of Chemistry, Lanzhou University, Lanzhou, 730000, P. R China
Pages 417-425 | Received 21 Apr 1990, Accepted 06 Nov 1990, Published online: 23 Sep 2006
 
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Abstract

In our survey of the chemistry of ZrCl4[sbnd]NaBH4, we have found that aldehydes and ketones can be regenerated from acetals and ketals at 30 °C in Et2O in high yield. The reaction mechanism was discussed

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