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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 21, 1991 - Issue 3
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Original Articles

The Synthesis of BIS(Phosphine)Tricarbonyliron(O) Complexes

Richard L. Keiter Department of Chemistry, Eastern Ill inois University, Charleston, Illinois, 61920
,
Ellen A. Keiter Department of Chemistry, Eastern Ill inois University, Charleston, Illinois, 61920
,
Carol A. Boecker Department of Chemistry, Eastern Ill inois University, Charleston, Illinois, 61920
&
David R. Miller Department of Chemistry, Eastern Ill inois University, Charleston, Illinois, 61920
Pages 473-478 | Received 25 Oct 1990, Accepted 26 Nov 1990, Published online: 23 Sep 2006
 
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Abstract

The high-yield synthesis of trans-Fe(CO)3L2 (L = PPh3, PPh2 H, P(n-Bu)3, PPh2 CH=CH, PPh2Me) can be acheived in one step by the reaction of Fe(CO), with L and NaOH in refluxing n-butanol. The reaction is selective for trans disubstitued complexes and is complete in 2 h.

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