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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 22, 1992 - Issue 7
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Original Articles

Ircn(II) Chloride Complexes with Some 2-Aminobenzimidazole Ligands

M. A. Mendiola Departamento de Quimica (C-VIII), Universidad Autónoma, Cantoblanco, 28049, Madrid, Spain
,
J. E. Masaguer Departamento de Quimica (C-VIII), Universidad Autónoma, Cantoblanco, 28049, Madrid, Spain
&
C. Molleda E. U. I. T. Forestal, Universidad Politecnica, 28040, Madrid, Spain
Pages 955-969 | Received 26 Jul 1990, Accepted 08 Apr 1992, Published online: 23 Sep 2006
 
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Abstract

The reactions of iron(II) chloride with primary amines 2-aminobenzimidazole (abi) and 2(2′-aminophenyDbenzimidazole (apbi) and the Schiff bases N-(p-methylbenzylidene)-2-aminobenzimidazole (pmbabi), N-(o-hydroxybenzylidene)-2-aminobenzimidazole (ohbabi), N-(benzylidene)-2(2-aminophenyl)-benzimidazole (bapbi) and K-(o-hydroxybenzylidene)-2 (2′-aminophenyDbenzimidazole (ohbapbi) yield complexes of general formula [Fe(L)Cl2] except for [Fe(pmbabi)2Cl2].

The complexes have been characterized by elemental analyses, conductivity and magnetic measurements and i.r., electronic and mass spectroscopic studies. The results suggest a pseudotetrahedral environment for the iron.

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