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Abstract
Metal(II)complexes, M(afs)2 and M(has)(H2O)2 [M = Mn, Co, Ni, Cu, zn; Hafs = 2-acetyl furansalicylaldazine and H2 has = o-hydroxyacetophenonesalicylaldazine]have been prepared and characterized. Magnetic and spectraldata such as electronic, ESR and IR were used to establish the stereochemistry and mode of bonding of the azines in the complexes. X-ray diffraction studies suggest a tetragonalunit lattice for Co(afs)2 and an orthorhombic unit lattice for Zn(afs)2 and Zn(has)(H2O)2.