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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 23, 1993 - Issue 6
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Original Articles

Polymer Complexes XXII. Metal Chelates Of Poly-[(5-vinylsalicylidene)-2-aminomethylpyridine]

A. A. El-Bindary Chemistry Department, Faculty of Science, Mansoura University, Demiatta, Egypt
,
A. Z. El-Sonbati Chemistry Department, Faculty of Science, Mansoura University, Demiatta, Egypt
,
M. A. Diab Chemistry Department, Faculty of Science, Mansoura University, Demiatta, Egypt
,
M. A. El-Ela Chemistry Department,Faculty of Engineering (Shobra), Zagazig University, Benha Branch, Egypt
&
S. A. Mazrouh Chemistry Department,Faculty of Engineering (Shobra), Zagazig University, Benha Branch, Egypt
Pages 875-888 | Received 10 Jan 1992, Accepted 03 Jan 1993, Published online: 23 Sep 2006
 
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Abstract

The reaction of 5-vinylsalicylidene-2-aminomethyl-pyridine (VSAPH) with Cu(II) resulted in a yellow-red Cu(II) polymer complex with very low magnetic moment at room temperature, while reaction with Co(II) produced a diamagnetic octahedral Co(III) polymer complex. NiCl2 gave a paramagnetic octahedral polymer complex, while the rest are diamagnetic with square planar and tetrahedral geometries.

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