Abstract
Coal chemical formation environment might result in different properties of hydrogen bonds in coal structure. The thermo stability, amount and types of hydrogen bond in six typical Chinese coal macerals were investigated by in situ vacuum Fourier transform infrared spectroscopy (FTIR). It was found that three types of hydrogen bond were involved in coal structure, which were OH-N, OH self associated, and OH tetrapolymer hydrogen bond. There was no correlation between the amount of three types of hydrogen bonds and extraction yield. The thermo stability of hydrogen bond in inertinite was stronger than that of vitrinite, especially the thermo stability of hydrogen bond in Pingshuo inertinite.
Acknowledgments
The authors greatly appreciate the financial support from NNSF of China (No. 20476068, 90410018, 20846002), Shanxi Natural Science Funding (No. 20051017), the Special Funds for Major State Basic Research Projects 973 (2005CB221207), NCET-05-0267, NCET-06-0261, and IRT0517 programs in MOE and Shanxi Returned Scholarship (2006-29).
Notes
a By difference.