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Research Article

Optimization and kinetic studies on biodiesel production from microalgae (Euglena sanguinea) using calcium methoxide as catalyst

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Pages 1497-1507 | Received 10 Dec 2017, Accepted 09 Nov 2018, Published online: 22 Nov 2018
 

ABSTRACT

The present work investigates the production of biodiesel from Euglena sanguinea microalgal bio-oil using calcium methoxide as a heterogeneous catalyst. The catalyst was synthesized and characterized by Fourier Transform Infra-red (FTIR) spectroscopy, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), basicity, and basic site strength analysis. Initially, bio-oil was extracted from mass-cultivated biomass obtained from Euglena sanguinea algae. It was further pretreated and transesterified using calcium methoxide catalyst at various experimental conditions by which an optimum yield of 94.83% was achieved. The catalyst yielded above 90% up to 5 cycles of recovery and recycling. The kinetic studies were investigated at various reaction temperatures to find the rate of reaction. The activation energy and pre-exponential factor for the transesterification reaction were found to be 99.33 kJ mol−1 and 1.07 × 1014 min−1 respectively. The properties of the produced biodiesel were within the limits of ASTM D6751 standard.

Correction Statement

This article has been republished with minor changes. These changes do not impact the academic content of the article.

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