Abstract
Hydrophobic and oleophilic polymethacrylates with moderate crosslinking have been increasingly used for oil cleanup. In view of oil recovery and absorbent reusability, the particle-like polymethacrylates are not satisfied completely due to flaccid absorption and unfacilitated assembly. Fiber is now considered as an optimal candidate for oil absorbents. This review summarizes the most promising approaches to fabricate polymethacrylate fibers including post-crosslinking, low-crosslinking (physical crosslinking or entanglement), and blend, and then illustrates the structure-property relations of as-prepared materials. The resulting polymethacrylate fibers are effective oil-absorptive materials because of fast absorption, facility, reusability, and easy disposal, pointing to the immense potential for future development.
Acknowledgment
The authors acknowledge the financial support provided by the National Natural Science Foundation of China (Grant Nos.: 50673077, 51103099 and 51103100), Tianjin Municipal Natural Science Foundation (Grant No.: 12JCQNJC01600), and the Research Fund for the Doctoral Program of Higher Education of China (Grant No.: 20111201120002). Our work was also supported by Handan Hengyong Protective & Clean Products Co., Ltd., Hebei Province, P. R. China.