Preparation of diglycolamide polymer modified silica and its application as adsorbent for rare earth ions

ABSTRACT

Three novel diglycolamide monomers were synthesized and polymerized on silica. The diglycolamide polymer grafted silica were used as adsorbents for rare earth ions. The effects of acid concentration, structure of monomer, initial solution concentration, contact time and coexisting ions on adsorption of rare earth ions were investigated in detail. It was shown that the adsorption capacity increased with increasing acid concentration. Three adsorbents exhibited selectivity for middle and heavy rare earth over light rare earth in different extent. The adsorbent prepared from the monomer having the largest alkyl substituent showed the lowest adsorption capacity but the highest selectivity for different rare earth elements (REEs). Adsorption data were well fitted to the Langmuir isotherm and pseudo-second-order models. The presence of high concentrations (100 fold) of coexisting metal ions, K(I), Cr(II), Cu(II) or Fe(III), does not decrease the adsorption for rare earth ions seriously.

KEYWORDS:

• Rare earth
• adsorption
• polymer-grafted
• diglycolamide

Disclosure statement

No potential conflict of interest was reported by the authors.

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Funding

This work was supported by the Beijing Natural Science Foundation under Grant [8172033] and Major Science and Technology Program for Water Pollution Control and Treatment under Grant [2017ZX07402001].