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Journal of Sulfur Chemistry Volume 32, 2011 - Issue 1
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Original Articles

Metallopolymer formation from the interaction of a hydrolyzed dithiolane-carboxylate ligand with Ag(I)

Sudershan R. Gondi Department of Chemistry, Southern Methodist University, PO Box 750314, Dallas, TX 75275-0314, USA
,
Hongming Zhang Department of Chemistry, Southern Methodist University, PO Box 750314, Dallas, TX 75275-0314, USA
&
David Y. Son Department of Chemistry, Southern Methodist University, PO Box 750314, Dallas, TX 75275-0314, USACorrespondence[email protected]
Pages 17-21 | Received 22 Apr 2010, Accepted 18 Nov 2010, Published online: 28 Jan 2011
 
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Abstract

On reaction with Ag(I), phenyl 1,3-dithiolane-2-carboxylate undergoes hydrolysis and assembles into a metal–organic coordination polymer. Crystals of the polymer were characterized by X-ray crystallography. The metallopolymer exists as a sheet-like structure consisting of twisted strands. An additional structural feature is an apparent Ag–Ag interaction (3.0679 Å) supported by the thiolane sulfur atoms. Carboxyl and triflate oxygen atoms are also key donors to the Ag(I) centers.

Acknowledgements

The authors thank the National Science Foundation (Grant No. 0092495) and the Welch Foundation (Grant No. N-1375) for support of this work.

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