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Journal of Sulfur Chemistry Volume 32, 2011 - Issue 6
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Original Articles

Novel atom-economic synthesis of thioselenophosphinates via three-component reaction between secondary phosphine sulfides, elemental selenium, and amines

Alexander V. Artem'ev A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Street, 664033, Irkutsk, Russia
,
Svetlana F. Malysheva A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Street, 664033, Irkutsk, Russia
,
Anastasiya O. Korocheva A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Street, 664033, Irkutsk, Russia
,
Yuriy V. Gatilov N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 9 Lavrentiev Avenue, 630090, Novosibirsk, Russia
,
Victor I. Mamatyuk N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 9 Lavrentiev Avenue, 630090, Novosibirsk, Russia
&
Nina K. Gusarova A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Street, 664033, Irkutsk, RussiaCorrespondence[email protected]
Pages 599-610 | Received 18 Aug 2011, Accepted 19 Sep 2011, Published online: 02 Nov 2011
 
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Abstract

An efficient, general, and atom-economic synthesis of organoammonium thioselenophosphinates has been developed by exploiting a three-component reaction between secondary phosphine sulfides, elemental selenium, and various amines. The reaction proceeds under mild conditions (70–75  °C, 1 h, EtOH) to afford thioselenophosphinates in 77–94% yields.

Acknowledgements

This work was supported by the Russian Foundation for Basic Research (grant no. 11-03-92003-HHC_a) and the President of the Russian Federation [programs for the support of leading scientific schools (grant NSh-3230.2010.3) and young Russian scientists (grant MK-629-2010.3)].

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Related Research Data

CCDC 832002: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Syntheses and Properties of Phosphinoselenoic Chlorides, Acids, and Their Salts
Source: Bentham Science Publishers Ltd.
Preparation and some reactions of thioacyl diphenylthiophosphinoyl and thioacyl diphenylphosphino sulfides
Source: Wiley
One‐Pot Atom‐Economic Synthesis of Thioselenophosphinates via a New Multicomponent Reaction of Secondary Phosphanes with Elemental Sulfur, Selenium, and Amines
Source: Wiley
Darstellung von [(C2H5)2NH2]3[PS3F]F und [(C2H5)2NH2]3[PS2SeF]F und Kristallstruktur der selenhaltigen Phase
Source: Wiley

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