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Articles

A one-pot synthesis of novel cyclic ketene dithioacetals from Nef-isocyanide-Perkow adduct

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Pages 679-685 | Received 24 Feb 2017, Accepted 22 Jun 2017, Published online: 07 Jul 2017
 

ABSTRACT

A novel synthesis of cyclic ketene dithioacetals through the reaction between phosphorous-based ketenimines [generated in situ from Nef-isocyanide-Perkow reaction], cyclic 1,3-dicarbonyl compounds, and carbon disulfide at room temperature, in moderate to good yields (65–80%), is described.

GRAPHICAL ABSTRACT

Disclosure statement

No potential conflict of interest was reported by the authors.

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