Homogeneous precipitation at solid/solution interface as a novel chemical route for synthesis of nanoparticles: application to Cd(II) and Pb(II) sulfides

ABSTRACT

Nanoparticles of CdS and PbS were prepared by a novel method in which a sparingly soluble salt of the metal is brought into contact with the preparation solution mixture, without mixing, to introduce Cd²⁺ or Pb²⁺ ion into the medium at infinitesimal doses. The aqueous solution mixture contained n-heptane; thioacetamide, as sulphide ion precursor; cetyltrimethylammonium bromide (CTAB), as capping agent; and n-butanol, as co-surfactant. At the solid/solution interface CTAB-capped nanometal sulphide is formed through a metathesis reaction in extreme dilute medium. UV-visible, FTIR, and X-ray diffraction spectroscopy, as well as transmission electron microscopy were used to characterise the nanoparticles. The results showed that in solution, the diameters of the prepared CdS and PbS are 2.67 and 1.87 nm, respectively. In crystalline form, the corresponding diameters are 3.8–6.6 nm, and 6.88–13.9 nm, respectively. The crystalline structure of CdS is cubic or hexagonal, while that of PbS is face-centred cubic. The FTIR studies proved that CTAB acted as a capping agent of the investigated nanoparticles.

KEYWORDS:

• Homogeneous precipitation
• solid/solution interface
• metal sulphide nanoparticles
• capping agent
• thioacetamide

Acknowledgments

The support received from Kuwait University through the Research Project SC 12/14, the facilities of the Research Sector Projects Unit (GS 02/01, GS 03/01, and GS 01/05), and the facilities of the Nanoscience Center of the Faculty of Science, is gratefully appreciated. The authors also acknowledge the Faculty of Graduate Studies, Kuwait University, for supporting the MSc student Abdulhakeem A. Ajadi.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by the Research Sector [grant number SC12/14], and College of Graduate Studies [MSc thesis of Abdulhakeem A. Ajadi], Kuwait University.