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Abstract
The release of heavy metals into the environment is a potential threat to water and soil quality as well as to plants, animals, and human health. In the current research work, organically functionalized mesoporous silicates (MSU-H) were prepared by the co-condensation between sodium silicate and organoalkoxysilanes in the presence of the nonionic surfactant triblock copolymer P104. The surfactant was used as a template for improving the porosity of hybrid gels. Synthesized materials were characterized. The surface morphology and textural properties of such materials varied with various kinds of groups in the channels. In this study, removal of some heavy metal ions from aqueous solution by adsorption process was investigated. Batch adsorption studies show that the adsorption capacity of metal ions on the functionalized silicates is more than that on pure MSU-H. Data show adsorption on synthesized materials is a time-efficient process, suggesting adsorption on external surface as well as the mesoporous process. Adsorption models of Langmuir, Freundlich, and Temkin depicted equal goodness for all adsorbents, whereas pseudo-second-order kinetics is in best agreement with experimental data.
Acknowledgements
The authors thank NISP Lab and FabLab at University of Maryland, College Park USA and Fatima Jinnah Women University, Rawalpindi Pakistan, for providing the necessary techniques for characterization of synthesized materials and their applications. Authors also gratefully acknowledge HEC (Higher Education Commission, Pakistan) for providing IRSIP fellowship to Saima Nasreen for pursuing her doctoral research at UMD, USA.
Notes
Presented at the 8th International Conference on Challenges in Environmental Science & Engineering (CESE-2015) 28 September–2 October 2015, Sydney, Australia