Abstract
Chemical reactions can lead to the expansion of the geomaterial because of the strong precipitation of minerals in the pores of the medium. The quantity and the variability of these reactions led to the development of several chemo-mechanical models. A generic chemo-poromechanical model is proposed to predict both the material degradation induced by various concrete pathologies and the environmental multi-factor impact on the macroscopic swelling. The model is based on the coupling between reactive transport (species diffusion and chemical reactions) and poromechanics. The mineralogy and the poromechanical properties are estimated by a hydration-micromechanics model which allows to consider the material effects. The main applications are dedicated to External Sulfate Attack and Delayed Ettringite Formation of cementitious material at mesoscale. The studies highlight the ability of the model to deal with complex and various phenomena such as coupling chemical reactions with calcium leaching, sulfate sorption and ettringite precipitation, and to consider their impact on the macroscopic expansion. Results also bring out the accuracy of the chemo-poromechanical model to simulate different swelling pathologies. The characteristic crack paths induced by differential strain, material impact, and swelling at the macroscopic scale, fit with experimental observations.
Acknowledgements
The authors would like to thank Alexandre Dauzères and Sidi Souvi for the help in the chemical modeling. We thank the two anonymous reviewers for their constructive critics, suggestions and comments.
Disclosure statement
The authors declare that they have no conflict of interest.
Data availability statement
The data that support the findings of this study are available from the corresponding author, Frédéric Perales, upon reasonable request.