Design and properties of seawater coral aggregate alkali-activated concrete

Abstract

To adequately develop the application of marine resources for island construction and sustainability in the construction industry, this paper explores the feasibility of using alkali-activated materials (AAMs) as alternatives to ordinary Portland cements (OPCs) for the application in seawater coral aggregate concrete (CAC) structures. Artificial seawater, coral aggregates, and slag-based AAMs containing 5 wt.% silica fume and 15 wt.% fly ash, were mixed to develop the alkali-activated seawater coral aggregate concrete (AACAC), with the workability (slump), compressive and splitting tensile strengths being studied. The influence parameters, such as the total cementitious material content, water-to-binder ratio, and sand rate, were considered through Taguchi orthogonal experimental design method. The experimental results indicated that the most important factor herein for the compressive and splitting tensile strengths of the AACAC was the total cementitious material content. The analysis of range and variance demonstrated that an optimal mixture for AACAC was determined to be a total cementitious material content of 500 kg·m⁻³, a water-to-binder ratio of 0.60, and a sand rate of 55%. Then, this optimal mixture was adopted to analyze the effect of the replacement ratio of sea sand for coral sand (R_s) on the workability, compressive and splitting tensile strengths of AACAC, and the cement-based CAC was selected as the reference. Finally, the microstructures of the paste-aggregate interface for the CAC and AACAC sliced specimens were detected by scanning electron microscopy (SEM). It can be concluded that increasing R_s improved the workability of the AACAC, but exhibited a very slight effect on its mechanical properties. Additionally, the utilization of AAMs can effectively reduce the broken of the coral aggregate inside the concrete due to improved interfacial transition zone (ITZ) between the aggregates and the pastes, thereby exhibiting a higher splitting tensile strength than that of the cement-based CAC.

Keywords:

• Alkali-activated materials (AAMs)
• seawater coral aggregate concrete (CAC)
• Taguchi method
• mix proportion
• mechanical properties
• microstructure

Acknowledgments

The authors gratefully acknowledge the funding support provided by the Natural Science Foundation of Jiangsu Province, China (Grant No. BK20191146), the National Natural Science Foundation of China (Grant No. 52078127), the Scientific Research Foundation of Graduate School of Southeast University (Grant No. YBPY2020), the Postgraduate Research & Practice Innovation Program of Jiangsu Province, China (Grant No. KYCX20_0113), the Fundamental Research Funds for the Central Universities (Grant Nos. 3205002102D and 3205002120D), and the China Scholarship Council (Grant No. 202006090078).

CRediT authorship contribution statement

Bai Zhang: Conceptualization, Investigation, Methodology, Data curation, Formal analysis, Writing - original draft, Writing - review & editing, Visualization. Hong Zhu: Resources, Supervision, Writing - review & editing, Validation, Funding acquisition, Project administration. Qiang Wang: Writing - review & editing, Validation. Kwok Wei Shah: Writing - review & editing, Supervision. Wei Wang: Writing—review & editing, Validation.

Disclosure statement

The authors declare that there are no commercial concerns or conflicts of interest in this paper.