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Reports

Laminated stone-inspired multi-layer crystal structure reinforced bamboo scrap/magnesium oxychloride lightweight composites

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Abstract

Magnesium-based aerated cement has the characteristics of noncombustibility and nontoxicity compared with traditional organic aerated materials, realizing low-carbon manufacturing and energy saving in building construction. However, the pore walls of ordinary magnesium-based aerated cement are thin and brittle and can easily collapse under force, limiting its application in energy saving. This study aimed to obtain low-cost, low-energy, lightweight, high-strength, flame-retardant, and heat-insulating thermal insulation materials. Inspired by the formation process of stacked stones, calcium stearate was adsorbed on solid particles, stabilizing the pore and forming independent lumps of gel-state crystals in this study. At the same time, the hydrogen bonds of hydroxyethyl cellulose were used to chemically stitch the dispersed crystals to form a dense laminated structure. The interfacial compatibility between bamboo scraps and magnesium oxychloride improved the load transfer efficiency. The results showed that the strength-to-weight ratio of the composites increased 2.5 times, and the softening coefficient increased about 2 times. In comparison, the mechanical properties and thermal insulation properties of the composites far exceeded those of most thermal insulation materials, providing a theoretical basis for their use in the field of multifunctional building materials.

Additional information

Funding

This work has been supported by the National Natural Science Foundation of China (31971743), Natural Science Foundation of Hunan Province, P.R. China (2023JJ10100), Hunan Provincial Technical Innovation Platform and Talent Program in Science and Technology, P.R. China (2019RS2040) and the Science and Technology Innovation Program of Hunan Province (2021RC4062).

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