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Original Reports

Overcoming the strength-ductility trade-off in refractory medium-entropy alloys via controlled B2 ordering

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Pages 813-823 | Received 13 Jun 2022, Published online: 08 Aug 2022
 

Abstract

Herein, we showed that controlled additions of Al, which provided a certain degree of B2 ordering, resulted in a ∼ 37%-enhancement of both yield strength and uniform elongation in Alx(NbTiZr)100-x (x = 0; 2.5; 5; 7.5 at.%) refractory medium-entropy alloys. The improvement of properties stemmed from the solid solution and short-range order strengthening, as well as from the alteration in a character of dislocation glide. The B2 ordering caused the formation of multiple dislocation bands and the activation of cross-slip, which improved the macroscopic stability of plastic flow and extended the strengthening stage, thereby postponing necking.

GRAPHICAL ABSTRACT

IMPACT STATEMENT

Controlled Al-induced B2 ordering helps overcome the strength-ductility dilemma in refractory medium-entropy alloys due to solid solution and short-range strengthening coupled with the dislocation motion changing.

This article is part of the following collections:
High-Entropy Materials: Mechanical property, Microstructure and Mechanism

Data availability statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgements

The work was carried out using the equipment of the Joint Research Center of Belgorod State National Research University «Technology and Materials» with financial support from the Ministry of Science and Higher Education of the Russian Federation within the framework of agreement No. No_ 075-15-2021-690 (unique identifier for the project RF-2296.61321X0030). The authors also thank Dr R. Eleti, Indian Institute of Technology Roorkee, for fruitful discussions, especially concerning the calculation of apparent activation volumes, and Dr S. Naumov, Belgorod National Research University, for aid in preparing the ingots of the alloys.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the Russian Science Foundation [grant number 21-79-10043] (https://rscf.ru/en/project/21-79-10043/).