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Research Article

Corrosion and microstructure of as-cast magnesium alloy AM60-based hybrid nanocomposite

, , , , &
Pages 181-199 | Accepted 09 Apr 2020, Published online: 14 Apr 2020
 

ABSTRACT

Two types of Mg alloy AM60-based composites containing (1) only 7 vol.% Al2O3 Fibre and (2) both 7 vol.% Al2O3 Fibre + 3 vol.% Al2O3 nano-Particle, named 7FC and MHNC-7F3NP, respectively, as well as the unreinforced matrix alloy AM60 were prepared by using the preform-squeeze casting technique. The microstructure of the matrix alloy AM60 characterised by optical microscopy (OM), scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS) consisted of primary α-Mg grains, eutectic β-Mg17Al12 phases and Al-Mn intermetallics, of which distribution were different from those in the composites. The reinforcement introduction refined the matrix grain structure of the composites significantly. The corrosion behaviours of the 7FC and MHNC-7F3NP composites and the matrix alloy were investigated by using the potential-dynamic polarisation test in 3.5 wt.% NaCl aqueous solution. Compared with the matrix alloy, the introduction of micron-sized alumina fibres decreased the corrosion resistance of the matrix alloy AM60 considerably due to the presence of excessive interfaces, while the high density of grain boundaries and the absence of noble precipitates such as β-Mg17Al12 phases and Al-Mn intermetallics at the grain boundaries in the composites should also be somewhat responsible for their poor corrosion resistance. The addition of the nano-sized particles led to almost no further reduction in the corrosion resistance of the MHNC-7F3NP.

Acknowledgments

The authors would like to thank the Natural Sciences and Engineering Research Council of Canada, and the University of Windsor for supporting this work.

Disclosure statement

No potential conflict of interest was reported by the authors.

Additional information

Funding

This work was supported by the Natural Sciences and Engineering Research Council of Canada and the University of Windsor.

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