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Inorganic and Nano-Metal Chemistry Volume 48, 2018 - Issue 2
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Original Articles

A new heterometallic Cd(II)-Na(I) coordination polymer: Synthesis, crystal structure and photoluminescent property

Li-Mei YouDepartment of Pharmacy, Mudanjiang Medical University, Mudanjiang, Heilongjiang, People's Republic of China
&
Jing GaoDepartment of Pharmacy, Mudanjiang Medical University, Mudanjiang, Heilongjiang, People's Republic of ChinaCorrespondence[email protected]
Pages 146-149 | Received 08 Jan 2017, Accepted 16 Jul 2017, Published online: 22 Feb 2018
 
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ABSTRACT

A new heterometallic compound, namely [CdNa(btc)(μ2-H2O)(H2O)]n (1 H3btc = 1,3,5-benzenetricarboxylic acid), was synthesized via the solvothermal reactions of Cd(NO3)2·4H2O, NaHCO3 and H3btc and further characterized by the elemental analysis, IR, powder X-ray diffraction analysis and single crystal X-ray diffraction analysis. The title complex crystallized in the monoclinic P21/c space group with a = 9.7056(4), b = 16.9780(6), c = 6.5046(3) Å, β = 103.658(5)°, V = 1041.53(7) Å3. This compound features a three-dimensional (3D) framework based on heterometallic 1D inorganic chains. The luminescent property of 1 has also been investigated.

Acknowledgments

The authors acknowledge the financial support of Mudanjiang Medical University.

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