Advanced search
Publication Cover
Inorganic and Nano-Metal Chemistry Volume 50, 2020 - Issue 10
Submit an article Journal homepage
65
Views
0
CrossRef citations to date
0
Altmetric
Articles

Two isostructural Cd(II) coordination polymers showing different adsorption behaviors toward methyl orange (MO)

Cai-Ying TianTianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin, P. R. ChinaView further author information
,
Ming-Ze LiTianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin, P. R. ChinaView further author information
&
Jing ChenTianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin, P. R. ChinaCorrespondence[email protected]
View further author information
Pages 1007-1011 | Received 17 Dec 2019, Accepted 03 Feb 2020, Published online: 26 Feb 2020
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Two isostructural Cd(II) coordination polymers (CPs), namely {[Cd(L)(H2O)2](ClO4)2}n (I) and {[Cd(L)(H2O)(dca)](ClO4)}n (II), have been synthesized by assembling a multidentate building block 3,4-bis(3-pyridyl)−5-(4-pyridyl)−1,2,4-triazole (L) with Cd(ClO4)2 in the absence or presence of sodium dicyanamide (Na(dca)). Single-crystal X-ray diffraction reveals that both CPs show the similar 2D-layered structures. Interestingly, they present distinct adsorption capacities (7% for I and 18% for II) toward the anionic dye methyl orange (MO). The results indicate that complex II shows higher adsorption ability, which may be ascribed to the charge effect of cationic framework.

Additional information

Funding

This work was supported by the Program for Innovative Research Team in University of Tianjin (TD13-5074) and Tianjin Natural Science Foundation (17JCYBJC22800).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Magnetic dendritic materials for highly efficient adsorption of dyes and drugs.
Source: American Chemical Society (ACS)
Magnetic Preyssler acid grafted chitosan nanoadsorbent for azo dye removal
Source: Wiley
Adsorption of methyl orange on mesoporous γ-Fe2O3/SiO2 nanocomposites
Source: Elsevier BV
Formulation and Stability Evaluation of Structure-Altered Paclitaxel Nanosuspensions Stabilized by a Biocompatible Amino Acid Copolymer
Source: American Scientific Publishers
From the conventional biological wastewater treatment to hybrid processes, the evaluation of organic micropollutant removal: A review.
Source: HAL CCSD
Controlled synthesis of NbO-type metal-organic framework nano/microcrystals with superior capacity and selectivity for dye adsorption from aqueous solution
Source: Elsevier BV
Sorptive removal of methylene blue from simulated wastewater using biochars derived from pulp and paper sludge
Source: Elsevier BV
CCDC 1969915: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Two isostructural Cd(II) coordination polymers showing different adsorption behaviors toward methyl orange (MO)
Source: Taylor & Francis
A facile approach to fabricate an immobilized-phosphate zirconium-based metal-organic framework composite (UiO-66-P) and its activity in the adsorption and separation of organic dyes.
Source: Elsevier BV
Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies.
Source: Elsevier BV
Electrospun Nanofibers Membranes for Effective Air Filtration
Source: Wiley
Degradation of methyl orange using Fenton catalytic reaction
Source: The Authors. Production and hosting by Elsevier B.V. on behalf of Egyptian Petroleum Research Institute.
Superlithiation of non-conductive polyimide toward high-performance lithium-ion batteries
Source: Royal Society of Chemistry (RSC)
Mesoporous carbons modified with lanthanum(III) chloride for methyl orange adsorption
Source: Elsevier BV
Selective adsorption of anionic dyes from aqueous solution by a novel β-cyclodextrin-based polymer
Source: Elsevier BV
From N-Substituted Thioamides to Symmetrical and Unsymmetrical 3,4,5-Trisubstituted 4H-1,2,4-Triazoles: Synthesis and Characterisation of New Chelating Ligands
Source: Wiley
Preparation and characterization of novel PVDF nanofiltration membranes with hydrophilic property for filtration of dye aqueous solution
Source: Elsevier BV
Design and construction of a ferrocene based inclined polycatenated Co-MOF for supercapacitor and dye adsorption applications
Source: Royal Society of Chemistry (RSC)
CCDC 1969914: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
Inside Back Cover: Charge Control in Two Isostructural Anionic/Cationic CoII Coordination Frameworks for Enhanced Acetylene Capture (Chem. Eur. J. 42/2016)
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.