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Inorganic and Nano-Metal Chemistry Volume 51, 2021 - Issue 2
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Articles

Assembly, structure and properties of three new multifunctional complexes derived from the naphthalene-based bis(pyridyl)-bis(amide) and benzenetricarboxylic acid

Hong-Yan Lina College of Chemistry and Chemical Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou, P. R. ChinaCorrespondence[email protected]
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,
Zi-Wei Cuia College of Chemistry and Chemical Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou, P. R. ChinaView further author information
,
Ming Jib Liaoyang Food Inspection and Testing Center, Liaoyang, Liaoning, ChinaView further author information
,
Ling Zenga College of Chemistry and Chemical Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou, P. R. ChinaView further author information
&
Qian-Qian Liua College of Chemistry and Chemical Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou, P. R. ChinaView further author information
Pages 272-279 | Received 07 Mar 2020, Accepted 25 May 2020, Published online: 26 Jun 2020
 
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Abstract

Three new metal(II)–organic coordination complexes, formula as [Cd3(btc)2(3-dpna)2(H2O)2]·8H2O (1), [Zn3(btc)2(3-dpna)2(H2O)2]·4H2O (2) and [Co3(btc)2(3-dpna)2(H2O)2]·2H2O (3) [3-dpna = N1,N4-di(pyridin-3-yl)naphthalene-1,4-dicarboxamide, H3btc = 1,2,4-benzenetricarboxylic acid], have been successfully synthesized by the hydrothermal methods. Complexes 1–3 exhibit similar 3D coordination networks based on the [M3(btc)2(H2O)2]n [M = Cd(II) for 1, Zn(II) for 2, Co(II) for 3] layers and the μ2-bridging 3-dpna ligand containing the naphthalene-bridging group, representing a 4,4,4-connected {42.64}4{64.82} topology. The photocatalyitc properties of complexes 1–3 toward degrading organic dyes, the fluorescent of complexes 1–3 and the fluorescent sensing activities of complexes 1–2 toward detecting metal ions have been studied. Additionally, the electrochemical and electrocatalytic properties of complex 3 have been investigated.

Additional information

Funding

The support of the National Natural Science Foundation of China (No. 21501013) is gratefully acknowledged.

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