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Research Article

Zinc ion-imprinted polymer based on silica particles modified carbon paste electrodes for highly selective electrochemical determination of zinc ions

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Pages 1698-1714 | Received 27 Jan 2020, Accepted 02 May 2020, Published online: 18 Jun 2020
 

ABSTRACT

In this study, Zn(II) ion-imprinted polymer was prepared on the surface of vinyl silica particles and applied for detection of Zn(II) ions using differential pulse voltametry. The ion- imprinted polymer particles were prepared by free radical polymerization. The prepared particles were characterized by different morphological and elemental techniques. The ion-imprinted particles were used to fabricate the carbon paste electrode as a zinc ions sensor. The modified zinc sensor showed linear response in the concentration range 6.12 × 10−9 to 4.59 × 10−8 mol L−1. The limit of detection and limit of quantification of the electrode were 1.351 × 10−8 and 4.094 × 10−8 mol L−1, respectively.

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Notes on contributors

Nilesh A. Khairnar

Nilesh Khairnar holds a Postgraduate Degree in Analytical Chemistry and currently pursuing Ph.D. degree under supervision of Dr. Gite at School of Chemical Sciences, KBCNMU, Jalgaon, India.  His areas of interest are imprinted polymer, electrochemical sensors, and nano particles for removal and sensing of toxic and heavy metals from water.

Harishchandra D. Jirimali

Dr. Jirimali has completed his B.Sc. and M.Sc. in Chemistry from North Maharashtra University Jalgaon (MS) India. He obtained Ph.D. in Integrated Biotechnology from Department of Chemistry, Sogang University Seoul, South Korea under the supervision of Prof. Woonsup Shin and continued as a Post-Doctoral fellow at the same department. He has completed his SERB Young Scientist Award project at School of Chemical Sciences, North Maharashtra University Jalgaon (MS) India. Currently he is working as Assistant Professor at Department of Chemistry, UKa Tarsadiya University, Surat – (GJ) India.

Kailas P. Patil

Kailas Patil holds a Postgraduate Degree in Organic Chemistry and currently working as an Assistant Chemical Analyzer in Regional Forensic Science Laboratory, Nasik – 422004.

Vikas V. Gite

Dr. Gite is working as Assistant Professor at Department of Polymer Chemistry, School of Chemical Sciences, Kavayitri Bahinabai Chaudhari North Maharashtra University (KBCNMU), Jalgaon, India.  He has completed is master and Ph.D. degrees in polymer chemistry from the same institute in 1999 and 2005, respectively and completed Post-Doctoral study from Hanyang University, South Korea in 2015.  His areas of interest are bio-based polymers, self-healing, control release, polyurethanes, etc. So far 9 Ph.D., 2 M. Tech., and about 20 M. Sc. students have completed their degrees under his supervision.  Besides this he also has experience to work in industry and Forensic Science Laboratory.

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