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Original Articles

FLOW INJECTION EXTRACTION SPECTROFLUORIMETRIC DETERMINATION OF ALUMINIUM AS THE TETRAPHENYLPHOSPHONIUM ALUMINIUM(III) 8-HYDROXYQUINOLINE-5-SULPHONATE

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Pages 1085-1093 | Received 10 Jun 2001, Accepted 13 Feb 2002, Published online: 02 Feb 2007
 

ABSTRACT

Aluminium was determined by flow injection spectrofluorimetry at 510 nm after excitation at 396 nm following extraction of tetraphenylphosphonium aluminium(III) 8-hydroxyquinoline-5-sulphoxinate into chloroform. The effects of diverse ions and masking studies are reported. The system has been applied to the determination of aluminium in steels by the method of standard additions.

ACKNOWLEDGMENTS

We wish to thank the University of Kasesart for support and leave of absence for one of us, (P.P.), The Higher Education Development Project: Postgraduate Education and Research Program in Chemistry, funded by The Royal Thai Government, for partial support for P.P., and the Science Library staff at The Queen's University of Belfast for assistance provided during and since this research, given at all times with unfailing cheerfulness and courtesy.

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