Abstract
A variety of functionalized pseudoglycal C-glycosides (C-pseudoglycals or C-hex-2-enopyranosides) have been obtained in excellent yield and stereoselectivity from the trimethylsilyl triflate (Me 3SiOTf) catalyzed reaction of trichloroacetimidate derivative 2 with silylated nucleophiles such as allyl and propargyl silanes and silyl enol ethers.
a Dedicated to Prof. Joachim Thiem on the occasion of his 60th birthday.
ACKNOWLEDGMENTS
This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. A. A.-H. A.-R. is grateful for an Alexander von Humboldt-Fellowship.
Notes
a Dedicated to Prof. Joachim Thiem on the occasion of his 60th birthday.