Remediation of a Heavy Metal-Contaminated Soil by Means of Agglomeration

Abstract

The feasibility of treating a heavy metal-contaminated soil by means of a solidification/stabilization treatment consisting of a granulation process is discussed in the present article. The aim of the study was to attain contaminant immobilization within the agglomerated solid matrix. The soil under concern was characterized by varying levels of heavy metal contamination, ranging from 50 to 500 mg kg⁻¹ dry soil for chromium, from 300 to 2000 mg kg⁻¹ dry soil for lead and from 270 to 5000 mg kg⁻¹ dry soil for copper. An artificially contaminated soil with contaminant concentrations corresponding to the upper level of the mentioned ranges was prepared from a sample of uncontaminated soil by means of spiking experiments. Pure soluble species of chromium, copper and lead, namely CrCl₃·6H₂O, CuCl₂·2H₂O and Pb(NO₃)₂, were selected for the spiking experiments, which were arranged according to a 2³ full factorial design. The solidification/stabilization treatment was based on an agglomeration process making use of hydraulic binders including Portland cement, hydrated lime and sodium methasilicate, which were selected on the basis of preliminary test runs. It was found that after 7 days of curing the applied treatment was able to efficiently immobilize the investigated heavy metals within the hydrated matrix. Good acid neutralization behavior was also observed, indicating improved matrix resistance to acid attack and decreased potential for metal leaching.

Keywords:

• Agglomeration
• Contaminated soil
• Heavy metals
• Solidification/stabilization