Immobilization of TiO₂ Nanopowder on Glass Beads for the Photocatalytic Decolorization of an Azo Dye C.I. Direct Red 23

TiO₂ supported on glass beads was prepared and its photocatalytic activity was determined by photooxidation of the commercial textile dye, C.I. Direct Red 23, in aqueous solution illuminated by a UV-C lamp (30 W). The progress of photocatalytic decolorization of the C.I. Direct Red 23 was studied by measuring the absorbance at λ_max = 507 nm by UV Vis spectrophotometer. The experiments indicated that both UV light and TiO₂ were needed for the effective destruction of the dye. The effect of pH on the rate of decolorization efficiency was followed in the pH range 2–12. Acidic pH range was found to favor the decolorization rate. The addition of a proper amount of hydrogen peroxide improved the decolorization, whereas the excess hydrogen peroxide quenched the formation of hydroxyl radicals (^•OH). The electrical energy consumption per order of magnitude for photocatalytic decolorization of the dye was lower in the UV/TiO₂/H₂O₂ process than that in the UV/TiO₂ process. In the real wastewater sample the efficiency of the method was determined by measuring the changes in the absorption spectra of the dye solution during photodegradation. Our results indicated that during the photooxidation process, the decolorization efficiency was more than 80% at irradiation time of 3 h.

Keywords:

• Advanced oxidation processes
• C.I. Direct Red 23
• EE/O
• Glass beads
• Immobilization
• Titanium dioxide.

ACKNOWLEDGMENT

We thank the university of Tabriz, Iran for financial and other supports.