Advanced search
Publication Cover
Journal of Macromolecular Science, Part A
Pure and Applied Chemistry
Volume 40, 2003 - Issue 1
Submit an article Journal homepage
186
Views
27
CrossRef citations to date
0
Altmetric
Original Articles

Ce(IV)-Ion Initiated Graft Copolymerization of Methyl Methacrylate onto Guar Gum

Brij Raj Sharma Center of Advance Studies in Chemistry of Forest Products, Forest Research Institute, Dehra Dun, India
,
Vineet Kumar Center of Advance Studies in Chemistry of Forest Products, Forest Research Institute, Dehra Dun, IndiaCorrespondence[email protected] [email protected]
&
P. L. Soni Center of Advance Studies in Chemistry of Forest Products, Forest Research Institute, Dehra Dun, IndiaCorrespondence[email protected] [email protected]
Pages 49-60 | Received 29 Mar 2002, Published online: 07 Feb 2007
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Graft copolymerization of methyl methacrylate onto guar gum was carried out in an aqueous medium using a ceric ammonium nitrate–nitric acid initiation system. The percent grafting (%G) and percent grafting efficiency (%GE) were determined as functions of the concentrations of ceric ammonium nitrate, nitric acid, methyl methacrylate, guar gum, polymerization temperature and time. Results are discussed and a reaction mechanism is proposed.

Acknowledgments

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Drag reduction effectiveness, shear stability and biodegradation resistance of guargum‐based graft copolymers
Source: Wiley
Synthesis, Characterization and Properties of Polyacrylamide-Starch Composites
Source: Wiley
Free radical grafting onto cellulose in homogeneous conditions. 2. Modified cellulose–methyl methacrylate system
Source: Elsevier BV
Pretreatments of Natural Fibers and their Application as Reinforcing Material in Polymer Composites—A Review
Source: Wiley
Czechoslovak discussion conference
Source: Wiley
The Theory and Kinetics of Specific Oxidation. IV. The Cerate 2,3-Butanediol Reactions in Perchlorate Solutions1
Source: American Chemical Society (ACS)
Grafting vinyl monomers to starch by ceric ion. I. Acrylonitrile and acrylamide
Source: Wiley
Perspective Study of Vinyl Grafting onto Leucaena glauca Seed Gum and Guar Gum by Hydrogen Peroxide Initiation
Source: Wiley
Structural aspects of poly(methyl methacrylate)-grafted β-chitin copolymers initiated by ceric salt
Source: Elsevier BV
Grafting onto Wool. XXVII. Graft Copolymerization of MixeD Vinyl Monomers by Use of Ceric Ammonium Nitrate as Redox Initiator
Source: Informa UK Limited
Extrusion-grafting starch onto vinylic polymers
Source: Wiley
CHAPTER 8 – GUAR, LOCUST BEAN, TARA, AND FENUGREEK GUMS
Source: Elsevier
Graft copolymerization onto jute fiber: Ceric ion‐initiated graft copolymerization of methyl methacrylate
Source: Wiley
Graft Copolymerization Onto Starch. 3: Grafting of Acrylamide Using Ceric Ion Initiation and Preparation of Its Hydrogels
Source: Wiley
Carboxymethylation of Cassia occidentalis seed gum
Source: Wiley
Influence of starch granule swelling on graft copolymer composition. A comparison of monomers
Source: Wiley
Grafting of 2-(Dimethylamino)ethyl Methacrylate onto Potato Starch Using Potassium Permanganate/Sulfuric Acid Initiation System
Source: Wiley
Modification of Gums: Synthesis Techniques and Pharmaceutical Benefits
Source: John Wiley & Sons, Inc.
The Oxidation of Pinacol by Ceric Sulfate
Source: American Chemical Society (ACS)
Studies on the ability of cellulosic materials to initiate graft copolymerization
Source: Wiley
Graft Copolymerization of Methyl Methacrylate on Potato Starch Using Potassium Trioxalatomanganate, K3[Mn(C2O4)3], as Initiator
Source: Informa UK Limited
WATER-SOLUBLE AMPHOLYTIC GRAFTED POLYSACCHARIDES. II. SYNTHESIS AND CHARACTERIZATION OF GRAFT TERPOLYMERS OF STARCH WITH ACRYLAMIDE AND [2-(METHACRYLOYLOX)] ETHYL DIMETHYL (3-SULFOPROPYL) AMMONIUM HYDROXIDE
Source: Informa UK Limited
Preparation and Application of Starch Graft Poly(vinyl) Copolymers as Paper Coating Adhesives
Source: Wiley
Graft copolymerization of acrylamide onto xanthan gum
Source: Elsevier BV
Infrared spectroscopy of graft polymers separated from graft copolymers of wool and silk with methyl methacrylate
Source: Wiley
Ceric-induced grafting of acrylate monomers onto sodium alginate
Source: Elsevier BV
Flocculants—an Ecofriendly Approach
Source: Springer Science and Business Media LLC
Mechanism of oxidation of cyclic alcohols by cerium (IV)
Source: American Chemical Society (ACS)
The Theory and Kinetics of Specific Oxidation. III. The Cerate--2,3-Butanediol Reaction in Nitric Acid Solution
Source: American Chemical Society (ACS)
A Simple Method for the Determination of the Degree of True Grafting in Graft Copolymerization of a Vinyl Monomer on Cellulose or Oxycellulose
Source: Informa UK Limited
Syntheses and characterisation of graft copolymers of maize starch and methacrylonitrile
Source: Elsevier BV
Water‐soluble copolymers. III. Dextran‐g‐poly(acrylamides) control of grafting sites and molecular weight by Ce(IV)‐induced initiation in homogeneous solutions
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.