FACILE, HIGH-YIELDING SYNTHESIS OF STEROIDAL CROWN ETHERS VIA PALLADIUM-CATALYZED CARBONYLATION REACTION

Andrea Petz Department of Inorganic Chemistry, University of Pécs, Ifjúság u. 6, Pécs, H-7624, Hungary

György Gálik Chemical Works of Gedeon Richter Ltd., Budapest, Hungary

Judit Horváth Chemical Works of Gedeon Richter Ltd., Budapest, Hungary

Zoltán Tuba Chemical Works of Gedeon Richter Ltd., Budapest, Hungary

Zoltán Berente Institute of Biochemistry, University of Pécs, Pécs, H-7643, Hungary

Zoltán Pintér Research Group for Chemical Sensors of the Hungarian Academy of Sciences, P.O. Box 266, Pécs, H-7624, Hungary

László Kollár Department of Inorganic Chemistry, University of Pécs, Ifjúság u. 6, Pécs, H-7624, Hungary

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Abstract

17-Carboxamido-androstanes possessing crown ether moieties attached to the amide functionality were synthesized from the corresponding 17-iodo-androsta-16-enes in palladium-catalyzed homogeneous aminocarbonylation reaction.

ACKNOWLEDGMENTS

L. K. thanks the Hungarian National Science Foundation (OTKA T23525) and Ministry of Education (FKFP 0242) for the financial support.

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FACILE, HIGH-YIELDING SYNTHESIS OF STEROIDAL CROWN ETHERS VIA PALLADIUM-CATALYZED CARBONYLATION REACTION

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FACILE, HIGH-YIELDING SYNTHESIS OF STEROIDAL CROWN ETHERS VIA PALLADIUM-CATALYZED CARBONYLATION REACTION

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ACKNOWLEDGMENTS

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